Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/2023
Title: A COMBINED EXPERIMENTAL AND THEORETICAL INVESTIGATION ON PYRAZOLONE DERIVATIVE AS CORROSION INHIBITOR FOR MILD STEEL IN 0.5 M SULPHURIC ACID MEDIA
Authors: Nalini D
Kohilah K S
Ramkumar, Sowmya
Keywords: acid corrosion
mild steel
pyrazolone
theoretical studies
sulphuric acid medium
Issue Date: 23-Apr-2014
Publisher: Sociedade Portuguesa de Electroquímicals, PortugaliaeElectrochimicaActa
Abstract: The inhibition action of the Pyrazolone Derivative (PYR) on the corrosion of mild steel in 0.5 M sulphuric acid was investigated by weight loss, polarization, impedance and SEM. Results obtained revealed that PYR performed excellently as corrosion inhibitor with efficiency of 91% at 11 ppm at 298 K. Its adsorption on mild steel obeys Langmuir and Temkin isotherm. Polarization curves indicate that PYR behaves as mixed type. The value of ΔG°ads indicates the spontaneous physisorption of PYR. The SEM results confirm the presence of a protective surface layer over the mild steel surface. The reactivity of the compound was analysed through theoretical calculation.
URI: http://dx.doi.org/10.4152/pea.201402109
http://localhost:8080/xmlui/handle/123456789/2023
ISSN: 0872-1904
Appears in Collections:International Journals



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