GROWTH, STRUCTURAL, DIELECTRIC AND OPTICAL CHARACTERISTICS OF GLYCINE PHOSPHITE SINGLE CRYSTALS

Abstract

Interesting compounds are formed when glycine reacts with inorganic materials. These compounds exhibit phase transitions with exciting dielectric and elastic properties. In this aspect, glycine with orthophosphorus acid forms glycine phosphite (GPI) single crystals. Good quality, optical transparent glycine phosphite (GPI) single crystals are grown from aqueous solution. GPI crystals have a wide range of nonlinear optical applications. The present work focuses on the growth of GPI from its aqueous solution by slow evaporation method. The PXRD (powder XRD) pattern recorded at ambient temperature shows the single phase nature of the grown GPI crystals and it exists in the monoclinic system with space group P21/a. Etching studies were carried out to know more about the growth morphology and FTIR spectra shows the presence of a variety of normal mode vibration of GPI crystals. Dielectric studies were carried out from 100 K to 383 K. the ferroelectric to para electric transition was observed at 201 K. The dielectric relaxation of the grown crystals was studied using Debye fitting. The activation energy associated with the transition was also calculated. As the GPI crystals are paraelectric at room temperature, no second order non linearity was observed.