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dc.contributor.authorParameswari K-
dc.contributor.authorRekha S-
dc.contributor.authorChitra S-
dc.contributor.authorKayalvizhy E-
dc.date.accessioned2020-08-24T06:22:44Z-
dc.date.available2020-08-24T06:22:44Z-
dc.date.issued2010-
dc.identifier.issn1647-1571-
dc.identifier.uriwww.scielo.mec.pt/pdf/pea/v28n3/v28n3a05.pdf-
dc.identifier.urihttp://localhost:8080/xmlui/handle/123456789/1024-
dc.description.abstractFour heterocyclic compounds, namely 4- phenyl-5-acetyl/carbethoxy-3-methyl-6hydroxyl-6-methyl-4,5,6,7-tetrahydro-2,1-benzoisoxazole and benzopyrazole (BIS1, BP1and BIS2, BP2), were synthesized and their influence on the inhibition of corrosion of mild steel in 1 M H2SO4 was investigated by means of weight loss, potentiodynamic polarization, electrochemical impedance (EIS) and scanning electron microscopy (SEM). The values of activation energy and free energy of adsorption of these compounds were also calculated. Adsorption obeys Langmuir adsorption isotherm. The IE of the compounds was found to vary with concentration and temperature. Synergistic effect was also investigated for the four compounds at 0.05 mM concentration by weight loss method in 1 M H2SO4 medium in presence of KI, KBr and KCl. Results obtained revealed that all the four compounds performed excellently as a corrosion inhibitor for mild steel in 1 M H2S04 and their efficiency attains more than 90% at 0.6 mM at 298 K. Polarisation studies showed them to be mixed type inhibitors.en_US
dc.language.isoesen_US
dc.publisherPortuguese Electrochemical Societyen_US
dc.subjectcorrosion inhibitionen_US
dc.subjectweight lossen_US
dc.subjectpotentiodynamic polarizationen_US
dc.subjectEISen_US
dc.subjectsynergism SEMen_US
dc.titleSTUDY ON THE INHIBITION OF MILD STEEL CORROSION BY BENZOISOXAZOLE ANDBENZOPYRAZOLE DERIVATIVES IN H2SO4 MEDIUMen_US
dc.typeArticleen_US
Appears in Collections:International Journals



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