THE ACID ADDUCTS HYDRAZINIUM 2-HYDROXYBENZOATE–2-HYDROXYBENZOIC ACID (1/1) AND HYDRAZINIUM 3-HYDROXY-2-NAPHTHOATE–3-HYDROXY-2-NAPHTHOIC ACID (1/1)

Abstract

The title molecular salts, N2H5+·C7H5O3−·C7H6O3 and N2H5+·C11H7O3−·C11H8O3, are acid adducts containing a hydrazinium cation, one molecule of a deprotonated acid and one molecule of a neutral acid. The two compounds contain essentially identical hydrogen-bond networks between the hydrazinium cation and the acid molecules, which define closely comparable two-dimensional layers in the structures. The planes of the aromatic rings within both structures are approximately parallel and the layers are stacked with comparable intermolecular interactions.