Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/4735
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dc.contributor.authorPrabha Devi, Balakrishnan-
dc.contributor.authorNatarajan, Arunadevi-
dc.contributor.authorNigam P, Rath-
dc.contributor.authorPonnusamy, Kanchana-
dc.contributor.authorThathan, Premkumar-
dc.date.accessioned2023-12-01T05:52:29Z-
dc.date.available2023-12-01T05:52:29Z-
dc.date.issued2023-01-16-
dc.identifier.urihttps://doi.org/10.1039/D2NJ05382A-
dc.description.abstractA new divalent Mg complex, hexaaquamagnesium(II) bis(6-oxo-1,6-dihydropyridine-3-carboxylate) ([Mg(H2O)6](C6H4NO3)2) (1), was synthesized by reacting Mg(NO3)2·6H2O with 6-hydroxypyridine-3-carboxylic acid (6-hpca) in the presence of aminoguanidine bicarbonate. Here, 1 was studied by elemental, infrared (IR), 1H NMR, 13C NMR, ultraviolet-visible (UV-vis), thermal, and single-crystal X-ray diffraction (SC-XRD) analyses. We discovered that 1 crystallized in the triclinic P[1 with combining macron] space group, whereas the Mg(II) ion exhibited six coordinated water molecules with octahedral geometry. Interestingly, 1 was used as a solid-state precursor for synthesizing Mg oxide (MgO) nanoparticles (NPs). Fourier transform infrared (FT-IR), UV-vis, powder-XRD, TEM, and energy-dispersive X-ray spectroscopic analyses were performed on the prepared MgO NPs. The results showed that the as-prepared MgO NPs were small (14 nm) and homogeneous. The antibacterial activity and antioxidant scavenging assays of 6-hpca, 1, and the MgO NPs against 2,2-diphenyl-1-picrylhydrazyl (DPPH) revealed that the MgO NPs had good biological properties. Furthermore, a sensitive electrochemical sensor was developed for improved glucose detection by modifying a glassy carbon electrode with the as-prepared MgO NPs. The MgO NPs demonstrated effective catalytic properties for the reduction of 4-nitrophenol to 4-aminophenol. The proposed approach is simple, environmentally friendly, and user-friendly.en_US
dc.language.isoen_USen_US
dc.publisherRoyal Society of Chemistryen_US
dc.titleA ONE-POT SOLID-STATE SYNTHESIS OF MGO NANOPARTICLES AND THEIR CATALYTIC, BIOLOGICAL, AND ELECTROCHEMICAL SENSOR ACTIVITIES: HEXAAQUAMAGNESIUM(II) BIS(6-OXO-1,6-DIHYDROPYRIDINE-3-CARBOXYLATE) AS A TOOLen_US
dc.typeArticleen_US
Appears in Collections:2.Article (95)



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